Effect of board density on bending properties and dimensional stabilities of MDF-reinforced corrugated particleboard

We investigated the bending properties of composite boards produced by reinforcing both sides of corrugated particleboard with medium-density fiberboard (MDF). Thickness swelling and linear expansion (LE) were measured to assess the dimensional stabilities of the composite board. Although the apparent density of the composite board was 0.48g/cm³, its strength was found to be equivalent to that of 18-type particleboard as described in JIS A 5908. The boards parallel/perpendicular anisotropy in strength was 0.9. The modulus of rupture (MOR) of the composite board increased with board density only up to a certain density, beyond which the MOR was constant. On the other hand, the thickness swelling of both corrugated particleboard and the composite board was smaller than that of flat-type particleboard, satisfying the JIS A 5908 standard of 12%. Linear expansion (soaking in water of ordinary temperature for 24h) of corrugated particleboard was 0.7%–0.9% in the parallel direction and 2.1%–3.1% in the perpendicular direction; hence, anisotropy in linear expansion existed in the corrugated particleboard. The linear expansion of the composite board was 0.6%–0.9% in the parallel direction and 1.8%–2.5% in the perpendicular direction. Although the LE of the composite board was lower than that of corrugated particleboard, it is necessary to improve the LE of composite board for practical use.     

乳化剂对4.5%高效氯氰菊酯水乳剂 物理稳定性的影响

以4.5%高效氯氰菊酯水乳剂为研究对象,探讨了乳化剂的种类、用量、亲水亲油平衡值(HLB值)和结构对水乳剂物理稳定性的影响。结果表明:当乳化剂种类选定后,在一定用量范围内,水乳剂的粒径随着乳化剂用量的增加而变小,粒径分布范围变窄,稳定性增强,粒径大小可作为筛选乳化剂最佳用量的指标;乳化剂的HLB值与水乳剂的粒径及粒径分布范围关系密切;乳化剂的结构和水乳剂的乳液抗聚并性存在相关性,适当增加亲油性的饱和碳链长度,有助于提高水乳剂的乳液抗聚并性,进而获得稳定的水乳剂配方。     

河西走廊中段干旱荒漠区土壤水热状况初步分析

通过对位于干旱荒漠区的张掖国家气候观象台土壤温湿度、土壤温度梯度、土壤导热率分析,结果表明:该地区土壤温度年变化、日变化较明显,受辐射变化影响大;土壤湿度年变化、日变化不明显,受降水影响较大.不管冬、春、夏季,土壤温度在晴天日变化较明显,但在雨(雪)天,日变化不明显.土壤湿度在晴天和雨(雪)天日变化均不明显,对降水有一...     

不同类型竹地板物理力学性能对比分析

对同一厂家生产的8种不同类型竹地板的物理力学性能进行了对比分析。结果表明：本色平压竹地板的物理力学性能最好;本色竹地板的物理力学性能优于炭化竹地板;平压竹地板的物理力学性能优于侧压竹地板、重竹地板及3 mm重竹贴面竹木复合地板;重竹地板密度最大,吸水率最低,在提高竹材利用率的同时,仍具有优良的物理力学性能,3 mm重竹贴面竹木复合地板可以有效降低重竹地板密度;重竹地板和3 mm重竹贴面竹木复合地板尺寸稳定性较差,炭化侧压竹地板更易使用受环境温湿度的影响。     

乙酰化处理对樟子松木材耐光性和热稳定性的影响

【目的】探讨乙酰化处理对人工林木材耐光性和热稳定性的影响,为木材颜色调控技术及高耐光染色木材的研发提供理论依据。【方法】以樟子松木粉为试样,加入乙酸酐和二甲苯溶液,在120℃条件下分别反应5,10,20,40,60 min,测试乙酰化处理时间对木粉增重率的影响;分别称取1 g经不同时间乙酰化处理的木粉和未处理木粉,置于 UV老化试验箱内辐射100 h,利用红外光谱分析 UV辐射前后乙酰化木粉化学官能团的变化,通过热重和扫描电镜分析乙酰化木粉的热稳定性及其形貌变化。【结果】随着乙酰化处理时间的延长,樟子松木粉的增重率呈现先增加后降低的趋势,在处理40 min 时木粉增重率最大;乙酰化木粉在1741 cm －1和1385 cm －1处的CO,C—H特征吸收峰强度均大于原木粉,处理时间40 min 时木粉的吸收峰强度最大;UV 辐射后,乙酰化木粉在1508 cm －1处木质素苯环特征吸收峰强度明显大于原木粉,处理时间40 min 时木粉的吸收峰强度最大,表明木粉经乙酰化处理后光稳定性得到提升;热重分析显示,经乙酰化处理后,木粉热分解所需的温度明显提高,表明乙酰化木粉的热稳定性好于原木粉;扫描电镜分析表明,乙酰化处理可增强木粉微观构造抵抗光劣化的能力。【结论】乙酰化处理能有效抑制樟子松木材的光降解反应并提升其热稳定性。     

腰果酚环氧稀释剂与E-51树脂共混体系固化性能研究

以天然腰果酚为原料制备了一种高活性腰果酚基环氧稀释剂(CDE),利用所制备的CDE与双酚A型环氧树脂(E-51)共混,再与甲基四氢苯酐进行交联固化反应,通过力学性能测试,研究了稀释剂含量对固化物性能的影响。实验结果表明:CDE对E-51有显著的稀释增韧作用;随着CDE含量的增加,固化树脂的玻璃化转变温度逐渐降低;当CDE的加入量为20%时,固化物的冲击强度及拉伸强度达到最大值,分别为19.17 k J/m2和56.81 MPa,弯曲强度为108.8 MPa。     

碱处理兴安落叶松材改性的研究

采用１％ＮａＨＣＯ＿３水溶液对兴安落叶松（Ｌａｒｉｘｇｍｅｌｉｎｉ）木材进行了处理，并用红外光谱、扫描电子显微镜和化学分析等方法对处理前后木材的尺寸稳定性、吸湿性、官能团和超微构造的变化进行了比较和分析。从而确定影响兴安落叶松木材尺寸稳定性的主要因素。本究研为兴安落叶松木材的改性和利用提供了理论依据。     

竹叶叶绿素的提取及其性质的稳定性

为了找到提取竹叶中叶绿素的最佳工艺条件,考察竹叶叶绿素的稳定性,通过单因素实验确定浸提溶剂种类原料颗粒度、料液比、浸提温度、浸提时间的合适范围,再利用正交试验法进行工艺优化. 结果表明,用无水乙醇提取竹叶叶绿素的最佳工艺条件是:原料颗粒度10～20目、料液比1∶5、浸提温度70℃、浸提时间7 h,竹叶叶绿素对紫外光、常见氧化剂(如H2O2)、Fe3 均具有较强的耐受性,在温度70℃以下以及近中性或偏碱性介质环境中性质基本稳定,遇Cu2 、Zn2 离子分别生成蓝绿色絮状沉淀和灰绿色颗粒状沉淀.     

Performance characterization of rigid polyurethane foam with refined alkali lignin and modified alkali lignin

The two kinds of rigid polyurethane (PU) foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in weight. The indexes of mechanical performance, apparent density, thermal stability and aging resistance were separately tested for the prepared PU foams. The results show that the mechanical property, thermal insulation and thermal stability for PU foam with modified alkali lignin are excellent among two kinds of PU foams and control samples. The additions of the refined alkali lignin and modified alkali lignin to PU foam have little effect on the natural aging or heat aging resistance except for decreasing hot alkali resistance apparently. Additionally, the thermal conductivity of modified alkali lignin PU foam is lowest among two kinds of PU foams and control samples. The alkali lignin PU foam modified by 3-chloro-1,2-epoxypropane could be applied in the heat preservation field.     

温室黄瓜发育期模拟模型的检验

针对作物生育期研究主要有3种方法:有效积温法、生理发育时间法和正弦指数函数法。试验选取不同温室不同茬口黄瓜的发育期数据和温室环境数据对3种发育期模拟模型方法进行验证。温室黄瓜发育期的预测结果表明,正弦指数函数法预测准确而稳定,回归估计标准误差(RMSE)在0.8~2.4d之间,以每日平均气温和每小时平均气温为输入值的生理发育时间法RMSE值分别在0.8~6.1和0.8~7.0d,有效积温法1.3~6.2d。基于以上验证结果,3种模拟预测发育期方法中,正弦指数函数法表现出较好的预测性和较强的机理性,适用于作物发育期的预测。